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EUBCE 2026 - Lénaïck HERVÉ - From Nanocatalysis to Heterogeneous Catalytic System: A Bottom-Up Strategy for Selective HMF Oxidation to FDCA

From Nanocatalysis to Heterogeneous Catalytic System: A Bottom-Up Strategy for Selective HMF Oxidation to FDCA

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Platforms for bio-based chemicals and polymers

Platforms for bio-based chemicals and polymers - Process developments

From Nanocatalysis to Heterogeneous Catalytic System: A Bottom-Up Strategy for Selective HMF Oxidation to FDCA

Short Introductive summary

This study introduces a nanocatalytic approach for the selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) under mild and environmentally friendly conditions. Using unsupported palladium nanoparticles as a "quasi-homogeneous" catalytic system, high activity and selectivity were achieved with air as the sole oxidant at atmospheric pressure. This configuration makes it possible to observe the intrinsic behavior of the active metal and to better understand the reaction mechanism, notably the involvement of hydroxyl species generated from water. These findings contribute to the design of more efficient and sustainable catalytic processes for the valorization of bio-based molecules.

Presenter

Moderator portrait

Lénaïck HERVÉ

IRCELYON, CNRS, FRANCE

Presenter's biography

I graduated with a MSc in sustainable energy production and storage from Université de Picardie Jules Verne and an engineering diploma from ESCOM Chimie. After a 5-year apprenticeship at REALCAT (hte in catalysis), I started a PhD in October 2023 at IRCELYON on HMF oxidation.

Biographies and Short introductive summaries are supplied directly by presenters and are published here unedited


Co-authors:

L. Hervé, IRCELYON / CNRS, Villeurbanne, FRANCE
F. Rataboul, IRCELYON / CNRS, Villeurbanne, FRANCE
C. Pinel, IRCELYON / CNRS, Villeurbanne, FRANCE
A. Cabiac, IFPEN, Solaize, FRANCE
M. Fernandez Espada Pastor, IFPEN, Solaize, FRANCE
L. Djakovitch, IRCELYON / CNRS, Villeurbanne, FRANCE

Session reference: 6BO.11.4