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EUBCE 2026 - Nadia CERONE - Biomethanol Synthesis from Biomass Syngas with an Innovative Lta-Zeolite Membrane Reactor

Biomethanol Synthesis from Biomass Syngas with an Innovative Lta-Zeolite Membrane Reactor

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Innovation in advanced processes for biofuels production: materials, mechanisms, and performances (part 1)

Biomethanol Synthesis from Biomass Syngas with an Innovative Lta-Zeolite Membrane Reactor

Short Introductive summary

In the presented work, a novel membrane reactor (MR) based on LTA zeolite was tested for methanol (CH3OH) synthesis starting from biomass gasification syngas enriched in H2 to meet the stoichiometric H2/COx ratio. The membrane was synthesized by the hydrothermal method and is characterized by an ordered microporous structure (3 – 5 Å) to selectively remove the water produced during methanol synthesis. The selective removal of one of the reaction products represents the strength of MR because it allows the system to overcome the limit imposed by the chemical equilibrium, pushing the reaction towards the products. This is reflected in the methanol yield, which in the MR is higher compared to conventional fixed-bed reactors.

Presenter

Moderator portrait

Nadia CERONE

ENEA Research Centre, Technical Unit for Trisaia Technologies, ITALY

Presenter's biography

Senior researcher at ENEA in development of technologies and processes of energy exploitation of biomass for electricity and biofuels. Expert of pyrolysis and gasification plants; hydrogen separation,LCA and project management.

Biographies and Short introductive summaries are supplied directly by presenters and are published here unedited


Co-authors:

N. Cerone, ENEA Research Centre, Rotondella, ITALY
G. Zito, ENEA Research Centre, Rotondella, ITALY
L. Contuzzi, ENEA Research Centre, Rotondella, ITALY
C. Florio, ENEA Research Centre, Rotondella, ITALY
G. Santilli, ENEA Research Centre, Rotondella, ITALY
M. Carnevale, ENEA Research Centre, Rotondella, ITALY
C. Ragone, ENEA Research Centre, Rotondella, ITALY
A. Romanelli, ENEA Research Centre, Rotondella, ITALY
A. Villone, ENEA Research Centre, Rotondella, ITALY
F. Zimbardi, ENEA Research Centre, Rotondella, ITALY

Session reference: 5AV.2.19